A River Runner’s Guide to Grand Canyon Geology IV: Whither the Supergroup?

We left off the last post having seen the complete Supergroup sequence of over two miles of Neoproterozoic and Mesoproterozoic sediments. The river never encounters the Neoproterozoic part, roughly half. These lie above the river on the North Rim side along the northeast shoulder of the Kaibab uplift that defines the first leg of the “W” of the Grand Canyon.

The river essentially makes an end run around the southern end of the Kaibab uplift. Where it turns the corner and heads towards the northwest, the river first encounters the Paleoproterozoic felsic intruded schists of the upper “Granite Gorge”. We don’t know how old these are. They have been baked at high temperature at a very considerable depth, possibly in several episodes. Each melt overprints the isotopic information.

We show above the river leaving the colored and hatched Mesoproterozoic Supergroup and entering the first Granite Gorge. The granite intrusions look like swimming amabae. Red Cardenas Basalt intrusions can be seen scattered about the Supergroup.This sequence from the green Escalante Creek member to Cardenas intruded Bass Formation foreshadows the rest of the Supergroup in the Grand Canyon.

Below we zoom in to the strange relationship between the Bass and the Cardenas intrusion. It is like there is some weak layer in the Bass the Cardenas easily intruded. We will see this same relationship at the very last Supergroup exposure in the Grand Canyon. A date of 1741 million years has been found the most recent melt of the Rama Schist near the left of the image.


The solid hatched Cardenas Basalt (Yc) can be seen sandwiched within the Bass. The Hatakai Shale lies above it; and finally the outlining top of Paleozoic Tapeats.

After turning the corner, the river never encounters the Supergroup again until Shinumo Creek; but up side canyons, particularly on the North Rim side, Supergroup rocks can be found. The shallower canyons have only the lowest Bass and Shinumo members, with maybe some Cardenas Intrusion. The deeper canyons expose the green Escalante Creek, but nothing higher in the Mesoproterozoic sequence is ever exposed in the Grand Canyon again.

Despite the names Bass Rapid and Bass Camp, the Bass Formation only just barely manages to reach the river at the Shinumo Creek Supergroup exposure below. The Bass lies over waning Vishnu Schist near the end of the Upper Granite Gorge, and only reaches the river with the help of a fault.

The Shinumo Creek exposure is tectonically complex. We have shown only the faults that control Supergroup extents. Here the Cardenas has intruded between the Bass and the Hatakai Shale. Over the Hatakai we get the namesake Shinumo and Escalante Creek (greenish blue here). A fault system has left more Shinumo above the Escalante Creek (Dox), including an outlier in the “Mordred Abyss” beyond the usual Tapeats boundary.


Below we zoom into the final Supergroup exposure in the Grand Canyon. Fittingly, it extends down to the river, where river runners may bid it proper farewell. You may recall a couple graphics back how the Cardenas intruded the bass in a ribbon, seemingly in some weak layer, next to the older Paleoproterozoic schists. Here the river decided to follow the ribbon of Cardenas.

The Middle Granite Gorge begins just below Specter Rapid, near the bottom of the graphic. We will explore the relationship between the Supergroup and the older schists and granites in the next post.

When we step back and contemplate the distribution of the Supergroup rocks in the Grand Canyon, we still find ourselves asking the same question that drove us to this exercise: What’s going on here?

Do the Supergroup rocks extend over the top of the Kaibab uplift where they will be exposed when the Paleozoic overburden eventually erodes away? We find no reason to believe they do not. The Mesoproterozoic members, sometimes called the Unkar Group, have no unconformities or intervals of time and erosion. They extend the entire length of the second leg of the Grand Canyon “W” at fairly consistent elevations up the southwest side of the Kaibab Uplift.

Do the Neoproterozoic members overlie the Mesoproterozoic rocks beneath the Paleozoic rocks in the Kaibab uplift? Maybe. Both Karlstrom (2012) and Huntoon (1999) draw sections that have the Neoproterozoic pinch out at the North Rim.

The above is from Karlstrom. It is a transect at about Nankoweap. It shows both the Mesoproterozoic (Y) and Neoproterozoic (Z) both pinching out somewhat up the Kaibab uplift towards the North Rim. It is unlikely that anyone has drilled to verify this and it strikes us as relying heavily on the notion of a flat surface before Paleozoic deposition.

We find the top of the Mesoproterozoic exposures up the creeks on the western side of the uplift routinely at 4200 feet, some 2000′ higher than shown for the Escalante and Shinumo members here.

Do the Supergroup members continue dipping down beneath the Paleozoic members on river left? The Karlstrom section suggests they do.

The next post will tackle another river runner’s bewilderment; the schists.





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A River Runner’s Guide to Grand Canyon Geology III: The Supergroup

A typical visitor to the Grand Canyon looks down from the rim through about a mile of sediments to the river. Most of these are Paleozoic sediments extending back about 515 million years. They appear to be level, although in a prior post we showed this levelness is an illusion of limited perspective.

This post is about over two miles of older sediments the typical visitor rarely sees. The Supergroup sediments are sloped at about 15 degrees due to uplift prior to the Paleozoic sediments deposited on top of them. River runners encounter these rocks in a very bewildering sequence we resolved to clarify on our last trip.

Above we show the eastern distribution of Supergroup rocks on an Arcmap image showing the grand “W” of the Grand Canyon. It can be seen that all of the Supergroup exposures are on the shoulders of the Kaibab Uplift, which reads dark green from the forest. The North and South Rim Visitor Centers are roughly centered on the eastern Supergroup.

Above we zoom into the first iteration on the river, and complete sequence of the Supergroup. This corresponds to the right hand first leg of the “W” before the river turns northwest in the first image. The Supergroup is composed of 17 members. Nine are Neoproterozoic (hatched horizontal) and eight are Mesoproterozoic (hatched diagonal). The colors follow the spectrum from red to violet

Sediments are difficult to date in general and Proterozoic sediments in particular because complex critters used for markers had not yet  evolved. A tiny volcanic ash deposit in the Walcott, the second Neoproterozoic member, dates to 742 million years ago. The Walcott is separated from the Sixty Mile formation above by an unknown amount of missing time and an unknown amount of erosion. The Sixty Mile Formation, currently a maximum of 200 feet thick, is preserved rarely, and is separated from Paleozoic rocks above by  unknown intervals of time and erosion as well.

The oldest and lowest Neoproterozoic member, the Nankoweap Formation, is also bounded by unknown intervals of time and erosion. Interestingly, the lowest Nankoweap contains wisps of sediments derived from the latest Mesoproterozoic Cardenas Basalt, showing that these intrusions got off to an early start.

The river never encounters the Neoproterozoic section (Sixty Mile through Nankoweap). These rocks lie up the Kaibab monocline and are separated at about the top of the Redwall from the river sequence by a large vertical offset along the Butte Fault. Like other places in the Grand Canyon, you can get multiple copies of the sequences where faults have made a mess of things. From the river, the Paleozoic sequence goes from Tapeats to top of Redwall. Above the top of Redwall and the Butte Fault lie members of Neoproterozoic Supergroup. Above the Supergroup it starts over again with Tapeats and climbs up the entire sequence to the North Rim.

The river first encounters the Supergroup in the Mesoproterozoic Escalante Creek Formation, which is not even the youngest. This is because a vertical offset along the Palisades Fault has allowed the younger strata to erode away. Below the fault the river marches through each of the inclined sedimentary strata beginning with the Ochoa Point Formation in turn.

The youngest Mesoproterozoic member, the Cardenas Basalt, is an intrusive rather than sedimentary layer. Below the Palisades Fault it intrudes all the sedimentary layers and only meets the river in dikes intruding the Bass and Shinumo members near the bottom of the second graphic above. The Cardenas is generically dated about 1.1 billion years ago. The oldest Mesoproterozoic member, the Bass Formation, contains some ash dated at 1.254 billion years ago.

In summary, the Supergroup extends from 1.25 billion years ago to some unknown time between 742 and 515 million years ago. Its current aggregate thickness is over two miles. It contains four unconformities, intervals of erosion, where an unknown amount of additional thickness was lost.

The lowest Paleozoic member, The Tapeats Sandstone, overlies the Supergroup and provides an outline. The bottom of the Tapeats is about 515 million years old. We show the top of the Tapeats as a tan line (close to its actual color). We extend it through the entire distribution of Supergroup rocks, even where it overlies even older schists and granites rather than the supergroup, because we feel it ties the narrative of Paleozoic deposition over a highly eroded Proterozoic surface together.

We have found many places where the Tapeats pinches out against the Supergroup, and also against older Paleoproterozoic rocks. We will argue that the Proterozoic surface was not entirely flat, and that these places where the Tapeats pinches out represent islands in the Tapeats Sea.

For context, we show above the distribution of middle and late Proterozoic rocks in the western United States. These formed at the same time as the Supergroup. The warmer colors are igneous granites and volcanics and the cooler colors are sediments. The “W” of the Grand Canyon is shown as a white path in the lower left. The large area of sediments at the top of the image extends well into Canada and is known as the “Belt Supergroup”. Correlation of these units with the Grand Canyon Supergroup is hindered by the same difficulties of dating sediments.

In the next post we will follow the river down through the remaining Supergroup exposures.





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A River Runner’s Guide to Grand Canyon Geology II: Muddy Creek and the Formation Problem

One might think that by now we would understand pretty well how the Grand Canyon formed. We don’t.

Central to the problems of how and when the current Grand Canyon formed is the Muddy Creek Formation, a bunch of freshwater lake sediments of late Miocene/early Pliocene age (5-6 my). These formed in a lake to the west of the Grand Wash Cliffs that form the western edge of the Grand Canyon and the Colorado Plateau.

The problem is that the Colorado River has cut through these sediments, limiting the age of the formation current river course (and the Grand Canyon) to sometime more recent.

A very good synopsis of the problem is presented by Joel Peterson (2008)

Click to access i1052-5173-18-3-4.pdf

A graphic from this paper above shows the distribution of the Muddy Creek Formation in relation to the “W” of the Grand Canyon. It also shows some ideas for the direction of Colorado River flow prior to the present. The Peterson paper rules out the “C” arrow because the Muddy Creek sediments match the Virgin River and not the Colorado River. An earlier “A” direction has been ruled out, leaving only “B”, the current course.

How do we resolve the current course with the Muddy Creek Formation? Where was the water going before 6 million years ago if not into the Muddy Creek Lake?

Humans are not the first Dam builders on the Colorado River. The infamous Lava Falls Rapid is formed by a lava dam. The latest work on Grand Canyon lava dams Crow et al (2015) identifies 17 lava dams within the last million years.

Click to access d8c55fbdfead6d612a6a0c2cf94ec07bde3e.pdf

The graphic above from Crow et al shows these extensive flows beginning at river mile 177.

These dams filled the river channel for  over a hundred miles in some cases. Volcanic remnants can be seen 1000 feet above the river. The effect of all this damming would be to slow the river and cause it to drop its sediment, keeping it out of Muddy Creek Lake even if significant Colorado River water leaked in to Muddy Creek lake through karst tunnels and around the dams. Karst tunnels dump impressive amounts of water from the canyon walls today at Thunder River, Tapeats Creek, and Vasey’s Paradise.

This scenario keeps the Colorado River  flowing in the only plausible direction, allows  the greater lateral erosion (and apparent geomorphic age) in the western Grand Canyon to take place above the lava lakes, fills Muddy Creek Lake with Colorado River water but not sediment, and allows the cutting of Muddy Creek sediments within the last few hundred thousand years after dam breaches. The only fly on this lovely picture is the lack of evidence for these sediments upstream.

We have a modern analogue for the fate of river sediments behind dams: the Lake Mead deposits exposed by the fall in lake level in the last few years. River runners have a great perspective on how fast this erosion takes place. The stuff is constantly falling in the river, and is often a dusty nuisance. We noticed significant erosion of these unstable sediments in a single year. One can easily imagine the whole lot washed away in a decade. Perhaps we should be looking for bathtub rings rather than sediments upstream.

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A River Runner’s Guide To Grand Canyon Geology

River runners have a different perspective on Grand Canyon geology. Remarkably, the put in at Lee’s Ferry is above the entire Grand Canyon sequence, and all the strata seem to emerge in turn from the river. This makes sense, but some strata disappear to the heights of the canyon walls, and others keep coming back to river level. The typical geological guide books offer vague mentions of undulations, but we wanted something more specific.

The Kaibab Limestone that visitors to both the North and South Rims stand on to admire the canyon emerges from the river at the end of the first mile. The six highest strata, from the Kaibab to the Redwall emerge, follow the river a while, and then disappear to the heights as the canyon deepens. They are never seen at river level again.

Here we have used geological maps with elevation contours to plot the elevations of the strata in transects from the river to the South Rim. The Hurricane Fault complex creates a second iteration of Vishnu to Redwall between the river and the South Rim.

The Muav Limestone emerges from the river, disappears to the heights, but comes back down to form the Muav Gorge before climbing back up for the rest of the canyon. The Bright Angel Shale returns to river level three times and the Tapeats Sandstone four. The Vishnu Complex of granite intruded bedrock makes four complete entrances and exits. The Supergroup is just too weird. It is a mile of sediments ranging from 1.25 billion to 725 million years old that overlies the Vishnu (1.75 to 1.68 billion years old) but suddenly disappears without explanation or further ado. The river encounters only a small part, briefly. The Supergroup will be the subject of a future post.

The 280 miles typically floated through the Grand Canyon basically makes a giant “W”. The first segment from Lee’s Ferry to Unkar, the second from Unkar to Dubendorf Rapid, the flattened middle segment from Dubendorf to Parashant Canyon, a segment from Parashant to Diamond Creek, and a final leg from Diamond Creek to the Grand Wash Cliffs.

In the first graphic we stretched the “W” into a straight line. It can be seen from the graphic that the river seems to cut through at least three ancient mountain ranges founded on elevated portions of Vishnu Complex. The first of these ranges corresponds very closely to the second segment of the “W” from Unkar to Dubendorf. This can be seen as the dark, forested region in the Google Earth image above where the highest rim elevations of the canyon are found. The roads to both the North and South Rims reach the canyon in this area, and it is commonly called the Kaibab uplift.

A second dark forested area can bee seen in Google Earth corresponding to the elevated area where the Kaibab through Hermit strata end, the Hurricane Fault Complex, and the beginning of the Lower Granite Gorge. It seems clear that ancient structures affect the course of the river.

It is peculiar that the ancient substructure telegraphs up through the younger strata. The current thinking is that the Vishnu (and Supergroup) were worn flat before the Cambrian Tapeats was laid down after 540 million years ago. Near Sockdolager Rapid, the Tapeats overlies both the Supergroup and adjacent Vishnu at the same altitude!

We are thinking that the recent uplift of the Colorado Plateau lifted the Vishnu cores of the ancient mountains more than other areas. Just another Grand Canyon mystery we will be exploring before returning to Radiative Altitudes.

Geological maps used for elevation Data:

Billingsley, G.H., and Priest, S.S., 2010, Geologic map of the House Rock Valley area, Coconino County, northern Arizona: U.S. Geological Survey, Scientific Investigations Map SIM-3108, scale 1:24,000.

  • Title: Geologic history and paleogeography of Paleozoic and early Mesozoic sedimentary rocks, eastern Grand Canyon, Arizona
  • Author(s): Blakey, R.C., and Middleton, L.T.
  • Publishing Organization: Geological Society of America
  • Series and Number: Special Paper 489, p. 81

Huntoon, P.W., Billingsley, G.H., Sears, J.W., Ilg, B.R., Karlstrom, K.E., Williams, M.L., and Hawkins, David, 1996, Geologic map of the eastern part of the Grand Canyon National Park, Arizona: Grand Canyon Association,  , scale 1:62,500

Billingsley, G.H., and Huntoon, P.W., 1983, Geologic map of Vulcan’s Throne and vicinity, western Grand Canyon, Arizona: Grand Canyon Association,  , scale 1:48,000

Billingsley, G.H., Clark, M.D., and Huntoon, P.W., 1981, Geologic map of the Hurricane fault zone and vicinity, western Grand Canyon, Arizona: Grand Canyon Association,  , scale 1:48,000

Huntoon, P.W., Billingsley, G.H., and Clark, M.D., 1982, Geologic map of the lower Granite Gorge and vicinity, western Grand Canyon, Arizona: Grand Canyon Association,  , scale 1:48,000



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The Temperature and Altitude of Radiation to Space III

We left of the last post having found that brightness temperature was hopelessly asymmetric to radiance in the main CO2 deviation from the Planck temperature. This discovery dashed all hope of using brightness temperature to determine the temperatures of the individual lines. We were able to replicate the form of the radiance deviation using the S-B equation, but the resulting temperatures fall well below atmospheric temperature in the deeper parts of the deviation.

Above the asymmetry of brightness temperature to tropical 70 km radiance.

Above excellent symmetry using S-B with emissivity of 2.25, but temperatures of ~80 K at the bottom of the deviation. According to the Planck curves the bottom of the deviation is about 220K.

Nothing about this effort has been easy, and the only check we can use on the accuracy of the Planck curves for determining the radiative temperatures of individual lines is to use the temperature of the MODTRAN tropical lapse rate. We report here the results of stepping up in altitude and comparing the strong lines as determined by eyechrometer against our densified Planck curves, with the lapse temperatures of the chosen altitudes.

Above we see the eyechrometer results from our 5 degree densified Planck curves. The two fairly flat lines at the top are the top corners of the CO2 deviation, 544 and 792. It can be easily seen from the second graphic below that these change little with altitude. They bound the CO2 deviation, are among the weaker strong lines, and abut “windows” on either side that radiate to space at surface temperature. The next two lines are 598 and 742. They both drop off rapidly with opposite curves through the troposphere, and flatline through the rest of the section. The next two are the stronger lines 618 and 720. They behave more like the by far strongest line (magenta 668). The last two are 648 and 688. They are the boundaries of the rotational bands that follow the fundamental bend at 668. They define the zone of zero transmission to the tropopause, and follow 668 (and the lapse) through the troposphere. At 20 km, where the prominent “spike” at 668 begins, they diverge.

An effort was made in the above and prior graphics to crudely use line thickness proportional to absorption intensity. This is the difference between the apparent Planck temperature and the lapse temperature.The strongest line (668) shows the least discrepancy and three strongest lines generally have the least discrepancy.

The discrepancy is least at one kilometer elevation. This is not surprising because at one kilometer the deviation from Planck is very small.

Above the CO2 deviations are compared at 1 kilometer, 5 Kilometers, 10 kilometers, and 70 kilometers. The strong absorption lines are easily traced up in altitude. As we progress upward in altitude, the apparent Planck temperature becomes increasingly different from the lapse temperature for most lines up to the tropopause. From the tropopause to the stratopause the differences all lines decrease and reverse sign. The sign of difference reverses again from the stratopause to maximum MODTRAN elevation at 70 km.

Shown again above for convenience, positive numbers mean apparent Planck temperatures above the lapse temperature, and negative numbers mean apparent radiance temperatures below the lapse temperature.

The radiances and lapse temperatures are both averaged over the tropics, so the systematic discrepancies should mean something. The striking feature is that the sign of the discrepancies follows the lapse rate.

When you see a trend of apparent Planck temperatures decreasing relative to the lapse temperature in the stratosphere as the lapse temperature increases with altitude, it must mean that a significant part of the radiance is coming from below. Reversing this logic explains the discrepancies in the cooling with altitude regimes above and below the stratosphere.

MODTRAN has output of total transmission and surface emission we used to try and sort this out. The MODTRAN explanation of total transmission is fairly straightforward:

Slit function direct transmittance for the line-of-sight (LOS) path including all sources of molecular and particulate extinction.

We take this to mean what you see is what you got from below at the virtual sensor at your chosen altitude. We believe this should exclude the radiance produced at your chosen altitude. This would seem to be everything needed, but we noticed peculiar structure in the output surface emission:

Surface emission directly transmitted to the sensor in units of W cm-2 sr-1 / cm-1. If the LOS terminates at the ground, this term is computed as the product of the Planck surface emission, the directional emissivity, and the path transmittance. If the LOS does not terminate at the ground but a positive temperature is specified for input TPTEMP, SURF_EMIS will contain the transmitted surface emission of a target object. If the LOS does not terminate at the ground and input TPTEMP is zero, then SURF_EMIS is zero.

This sounds a lot like total transmission, but it seems unclear whether the surface in direct line of sight must always be the ground, or whether a different altitude and temperature can be specified.

We tried the “Ground Temperature Offset” feature to set one kilometer of lapse as the “surface” TPTEMP, but this merely moved identical radiance 6 degrees (the lapse) down the apparent Planck curves.

Above we find that Surface Emission and Transmission are very similar except in the lower wave numbers of the CO2 deviation, with emission being somewhat stronger than transmission where they diverge. We have no explanation and find neither useful in determining the radiance from below that seems to drive the difference between apparent Planck and lapse temperatures. In the zero transmission and emission zones, which are the same, there is still radiance from below. This radiance must come from surfaces above the ground.

In the next post we will take a stab at gauging above ground radiance (and possibly emissivity) using downward radiance.



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The Temperature and Altitude of Radiation to Space II

We left off the last post having accommodated MODTRAN radiance to the Planck curves, and having promised to derive the temperatures of the individual lines from an inversion of the Planck radiance formula to give the Planck brightness temperature.

Unfortunately, we were unable to make this work. Several different formulae for brightness can be found that yield somewhat different results, but they all show conformance to the general shape of the CO2 radiance deviation.

We decided to use the following two because despite their different approaches, when scaled they become identical.

Below is what we get using the first equation above not scaled:

We really don’t know what to make of this. The systematic decrease in brightness from lower to higher wave numbers across the CO2 deviation in relation to radiance seemingly gives little hope that useful temperatures can be gained this way.

The good news is that a fresh look at the Stephan-Boltzmann approach to temperature using an emissivity slightly above .2 gives a far more satisfying result.

Staley and Jurica (1970) derived a full column emissivity for CO2 of .2. We are frankly astonished that by tweaking this slightly higher we were able to get such good agreement across the ~250 wave numbers of the CO2 deviation. Perhaps .225 is the correct column emissivity. At any rate, we will use this approach to get our temperatures henceforth.



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The Temperature and Altitude of Radiation to Space

This post was begun some time ago and we experienced so much trouble replicating the MODTRAN Planck curves that two rambling subsequent posts transpired recounting the misadventure. Here, and here. We eventually concluded that the Planck curves in the MODTRAN output graphic can be satisfactorily replicated if the MODTRAN line radiances are scaled by a factor of 10,000. No mention of this tidbit is made in the MODTRAN documentation or many preceding graphics from IRIS satellite measurements plotted against Planck curves.

Having replicated the curves vs radiances, it should now be possible to use brightness temperature to determine altitude by lapse, after similarly scaling the radiances. Brightness temperature is simply an inversion of the Planck formula to give temperature rather than radiance.

We resume the post below as originally begun. Hold on tight, nothing has been smooth sailing so far.

We left off a prior post with the graphic shown again below. It plots MODTRAN CO2 only (the other absorbing gasses zeroed out) 410ppm CO2 total upward IR radiation in one kilometer increments from the surface (1 meter) to 70 km.

This is well and good to establish that several watts of CO2 radiance to space is coming from the stratosphere, but what altitudes and which CO2 absorption bands are involved?

We established from the graphic above that the deepest part of the CO2 deviation from the surface Planck curve conforms to and radiates at the 220K Planck curve.



This portion of the CO2 radiance deviation conforming to the 220K Planck curve corresponds to the rotations linked to the fundamental bending mode of the CO2 molecule.

But what is MODTRAN actually seeing from 70 km? The 70 km line of sight crosses 220K on the lapse curve three times! This is where the ability to calculate the emission temperature from the radiance might be helpful, particularly at temperatures that don’t cross the lapse curve three times.

In the graphic above we have labelled the significant absorption lines of the CO2 molecule in a CO2 only greenhouse world. MODTRAN has plenty of resolution to distinguish these according to the table below.

If we use our eyechrometer on our densified Planck curves below, we can get approximate radiative temperatures for the significant lines.

If CO2 were a good blackbody, we would be able to check these radiative temperatures using the Stephan-Boltzmann equation. We tried this but it yielded temperatures far out of range for our atmosphere. CO2 is a lousy blackbody with a column emissivity of about .2. Applying this correction was no help.

In the next post we will check these eyeball temperatures against similarly scaled brightness temperatures.



Posted in Greenhouse Spectra, MODTRAN, Radiance | 1 Comment

Alalyzing the MODTRAN Planck Curves

This post reports on some progress on resolving our difficulty replicating MODTRAN Planck curves in a prior post. In a personal communication, Dr. David Archer kindly provided the spreadsheet used to produce the MODTRAN curves.

The standard wave number Planck formula is:

Dr. Archer’s MODTRAN formula is:

We have reddened the factors where Dr. Archer’s intensity differs from Planck radiance. Assumptions can be dangerous, but we assume that when MODTRAN “Raw Model Output” is in units of radiance, the graphic is also in units of radiance.

The problem we encountered was that in consistent units of radiance, we could not reproduce the MODTRAN graphic. We got the result below:

Which differs significantly from this:

Our intention had been to increase the density of Planck curves for better resolution of the radiative temperatures in the CO2 deviation.

Remarkably, we discovered that when the factor of Pi is removed from Dr. Archer’s equation, it yields identical values to the standard Planck equation we have used.

What this must mean is that Dr. Archer’s factors of 10^8 in the dividend and 100 in the divisor are symmetrical. If so, why bother?

We discovered that the MODTRAN graphic can be acceptably reproduced in units of radiance on the same axis if the Total Radiance output is scaled by 10^4.

That’s a lot of scaling. We have done our share of scaling to make things comparable, but always with far more modest scaling factors. At 10^4 you approach a realm where scaling matters for stuff like quantum effects.

We also discovered that an eerily visually similar result can be achieved on separate axes without scaling if another .2 increment (of 10^-5 W/m2) is added to the Total Radiance axis. This essentially stretches the axis, thereby compressing the CO2 deviation.

Wow. What does all this have to say about the reliability of temperatures implied by the relationship between the Planck curves and the CO2 deviation? Ultimately the scaling (or compressing) exercise is about getting the Total Radiance away from the deviation close to surface temperature. Nobody believes that over a wide area like the tropics, anything is radiating 10-15 degrees above surface temperature, as our first efforts implied.

Once you take the plunge of setting the top of the deviation reasonably below surface temperature, things appear to fall into place nicely. The shape of the P and R rotations on either side of the fundamental bend, and the top corners of the deviation match the Planck curves too well to deny a relationship.

The graphic below appears on the University of Chicago MODTRAN website.

It is a validation of the program against measurements over the Sahara by the IRIS satellite. It is in units of radiance. (Having the N from radiance decide it needed to appear in the middle of the graphic is something that would happen to me!)

Most of the old satellite radiances are plotted against Planck curves. It is dissapointing that no mention is ever made that  the measured radiances are grossly scaled or massaged to fall in line.


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Trouble with Trancendental Numbers

The title of this post was supposed to be The Temperature and Altitude of Radiation to Space. With a bit of luck and perseverance that post will happen, but we’ve had so much trouble, the trouble itself seems to warrant a post.

We had discussed the temperature of radiation to space in a “mark with chalk, cut with a chainsaw” kind of way based on MODTRAN graphics below.

We see that CO2 takes a gap toothed bite out of the Planck radiation curve and that the bottom of the deviation conforms to and matches the 220 K Plank curve in a general sort of way. The “P” and “R” rotations surrounding the fundamental bend conform generally to 220 K, but the fundamental “Q” branch itself jumps up to something like 240 K, and the other absorption lines fall unsatisfyingly between the 20 K Planck increments. We want a much more precise way to judge the radiative temperature.

Our first approach was to try to reproduce the MODTRAN graphic with 5 K temperature increments. When you push the “Show Raw Model Output” button you get Radiance in 2 wave number increments. We then sought to plot the Plank curves for the same increments according to the equation:

We got beautiful curves.

Unfortunately, our MODTRAN gap toothed bite was some 4 orders of magnitude less than the Plank units, and even when scaled on a secondary axis did not match the MODTRAN graphic in either implied temperature or units. Rats!

In trying to understand why, we noticed that the MODTRAN graphic is in units of Intensity W/m2/cm-1. These units are commonly used for Irradiance or incident radiation as opposed to Radiance or radiant exitance per solid angle. In fact. Planck curves in units of Irradiance match the units in the MODTRAN graphic, but this left the unwelcome task of converting the model output in Radiance to Irradiance. This is a can of worms in its own right, and involves transcendental numbers.

Even if we could reproduce the MODTRAN graphic with 5 degree Planck increments, we would still be interpolating. What we really want is a Planck temperature for each wave number’s total radiance. Brightness temperature seemed to fit the bill. It basically treats each wave number’s  total radiance as the maximum intensity of a new Planck curve to derive the temperature.

This basically inverts the Planck equation to give temperature. The I is confusingly intensity. We plugged in MODTRAN total radiance for and got:

Using the equation above we got brightness temperature in the ridiculously low units on the left, somewhat like of the microwave background radiation from space. We found another brightness equation that used base 10 log and used the physical constant “C1”, which is 2hc^2 in a way unfathomable to us. Remarkably, the two different equations scale closely, with Eq. 2 giving units to the right in the range of nuclear fusion in the sun.

Brightness and radiance scale closely, with the difference increasing in shorter wavelengths.

A fine kettle of fish! We still don’t have reasonable temperatures by wave number.

For now, we are blaming our travails on transcendental numbers. Numbers have no business being transcendental. They should unfailingly hold their values. Using the constant e implies a symmetry. Perhaps emergent properties of e^x in both the Planck and brightness equations are messing us up. (Wink)

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A Brief History of Muddled Thinking about the Greenhouse Effect

We humans kick up a lot of dust and burn a lot of stuff. A concept developed in the 1970’s was the “human volcano”. There is a lot of truth in this analogy. Back then, despite dead wrong rants, the sober scientific consensus was that it was unclear whether the net effect of the human volcano was to warm or cool the planet.

“At the present rate of nitrogen build-up, it’s only a matter of time before light will be filtered out of the atmosphere and none of our land will be usable.”

The quote above from Kenneth Watt, a self-appointed and widely read guru, in 1970. He was worried about cooling. Nobody worries much about “nitrogen build-up” these days, nor cooling; we have new witches to burn.

Al Gore likened the CO2 greenhouse effect to a blanket, keeping the planet warm by reducing energy loss to space. This might work if the blanket was a “space blanket”with a coating to reflect the dim light radiated from the surface back down. If you have ever used a space blanket to stay warm, you will know that it helps, but you would much rather have a down blanket. This is because conduction and convection are very important as well as radiation, and the down blanket reduces conduction and convection better than a space blanket.

Somewhat more sophisticated came the argument that rather than a blanket, the greenhouse effect relies on pushing the “net radiative altitude” higher. Since the troposphere cools with altitude, and radiative intensity varies to the fourth power of temperature, pushing this radiative altitude higher would reduce radiation to space. We will show that significant CO2 radiation to space comes from the stratosphere where temperature increases and radiation to space increases to the fourth power of increasing temperature with increasing concentration.

According to MODTRAN, as seen from the altitude of polar orbiting satellites at 70 km, the fundamental bend of CO2 (and its rotations) radiates at a temperature of 220K. This temperature corresponds to an altitude of 12-13 km at the tropical lapse rate. The atmosphere continues to decline in temperature in the tropics to 17 km, where the lapse suffers a relapse and the atmosphere begins increasing in temperature with altitude.

If you set MODTRAN to 410 ppm CO2, and set all the other greenhouse gasses to zero; you can vary the altitude to see where the CO2 radiance is coming from.

Above you can see that the total IR upward flux looking down from the tropopause at 17 km is 397.21 W/m2. You can also see that without the other absorbing gasses, the planet radiates at the Planck curve for surface temperature except for the deviations caused by CO2. The lowest part of the CO2 deviation is seen radiating at the temperature of the 17 km altitude, about 195K, as seen from the blue lapse curve to the right.

When we jump up to 70 km we see that the upward IR flux increases to 400.35 W/m2. This means that 3.14 W/m2 of the CO2 radiance polar orbiting satellites at 70 km see is coming from the stratosphere. As you can see from the blue lapse curve to the right, temperature increases with altitude in the stratosphere. The bottom of the CO2 deviation conforms to and radiates at the 220K Planck curve, a temperature 25 degrees higher than the bottom of the deviation at 17 km. In the tropical atmosphere, 220K matches an altitude of  24 km in the stratosphere.

When we drop down to 24km the upward flux is 398.15, meaning that 2.2 W/m2 of the CO2 radiance seen from 70km takes place above 24 km.

We decided to continue the exercise above and record the MODTRAN upward radiance at one meter and thereafter at 1 km increments to 70 km. It can be seen that CO2 radiance increases in the lower stratosphere and then levels out beginning at 43 km. Seemingly, 43 km is the last inflection point in CO2 radiation to space.

We began this post with examples of muddled thinking about the impacts of human absorptive gasses in the atmosphere. We end the post having presented data indicating that we need a far more nuanced approach.






Posted in Climate, Greenhouse Effect, Greenhouse Spectra, MODTRAN | 6 Comments